Product ID:4424 CALK STRIP, BLACK
MSDS Date:04/15/1993
FSC:8030
NIIN:00N073514
MSDS Number: CCBCV

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: MART2

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

POLYAMINE AMIDE; (POLYAMINE)

Fraction By Weight: 5%

OSHA PEL N/K

ACGIH TLV: N/K

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 2-5%

OSHA PEL 0.1 MG/M3 (MFR)

ACGIH TLV: 0.1 MG/M3 RDUST

CALCIUM CARBONATE

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 40%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR
SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE
EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION AND
PERSONAL PROTECTIVE EQUIPMENT. AC UTE:IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. REDNESS AND ITCHING OR BURNING SENSATION MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON
CARCINS, (SUPP DATA)
Effects of Overexposure:HLTH HAZ:INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE. CHRONIC:LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST,
WHICH CAN OCCUR ONLY WHEN SANDING OR ABRADING THE DRIED FILM, MAY
CAUSE LUNG DAMAGE (SILICOS IS).
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:SEEK MEDICAL ATTENTION.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:TRANSFER TO APPROPRIATE CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN. USE ONLY
W/ADEQUATE VENTILATION. AVOID BREATHING VAPOR & SPRAY MIST. AVOID
CONTACT W/SKIN & EYES.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED NIOSH
APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR FOR PROTECTION
AGAINST MATERIALS IN INGREDI ENTS.
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
EXPLAN OF CARCIN:1994:ANTICIPATED TO BE CARCINOGEN. VENT:1910.94,
1910.107, 1910.108.

Vapor Density:HVR/AIR
Spec Gravity:1.5
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:<5(WT)

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODUCTS IS NOT HAZARDOUS AS
DEFINED UNDER THE RCRA (40 CFR 261). DISPOSE OF I/A/W FEDERAL,
STATE & LOCAL REGULATIONS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.